• Synthesis and characterisation of a heterodinuclear ruthenium(II)-palladium(II) complex with two different cyclometallating sites
    A. Jouaiti, M. Geoffroy and J.-P. Collin
    Inorganica Chimica Acta, 245 (1) (1996), p69-73
    DOI:10.1016/0020-1693(95)04799-9 | unige:2819 | Abstract | Article PDF
A bis-cyclometallating ligand bearing two different terdentate coordination sites (N---C---N: dipyridyI-benzene; P---C---P: diphosphaalkenebenzene moieties) has been synthesised. Selective reactions of appropriate metal complex precursors afforded a heterodinuclear ruthenium(II)-palladium(II) complex characterised by 1H, 13P NMR spectroscopy and FAB-MS techniques. We have compared its electrochemical and spectroscopic properties (absorption and emission) with the individual ruthenium(II) and palladium(II) subunits.

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